Handbook on the Physics and Chemistry of Rare Earths..

Handbook on the Physics and Chemistry of Rare Earths.



Download Handbook on the Physics and Chemistry of Rare Earths.



Handbook on the Physics and Chemistry of Rare Earths. . pdf ebook
Publisher: Elsevier
Language: English
Page: 411
ISBN: 0444532218, 9780444532213

This continuing authoritative series deals with the chemistry, materials science, physics and technology of the rare earth elements in an integrated manner. Each chapter is a comprehensive up-to-date, critical review of a particular segment of the field. The work offers the researcher and graduate student a complete and thorough coverage of this fascinating field.REVIEW:.Highly experienced authors have written each review usually at a level suitable for advanced postgraduate students and research workers from a variety of fields. With the great richness of information involving references to other review articles written from different points of view, the books are an important reference source and should be on the shelves of most libraries. (Journal of Applied Crystallography) · Authoritative · Comprehensive · Up-to-date · Critical

From the Back Cover

The first chapter (241) in this volume of the Handbook on the Physics and Chemistry of Rare Earths gives a theoretical overview of the dual nature of 4f states in the lanthanides, which may either be part of the valence states or be inert and form part of the core. First principles theory is supported by relevant experimental data, thus providing a coherent picture of the present state-of-the-art of this fascinating subject. Chapter 242 is a compilation of temperature-dependent data about crystallography and crystal chemistry of over a hundred of aluminates (RAlO3) and gallates (RGaO3) and their solid solutions. The reader should find a systematic analysis of structures and distortions, as well as detailed phase diagrams of numerous RAlO3 - R'AlO3 and RGaO3 - R'GaO3 systems both interesting and useful. The last chapter (243) is focused on the chemistry of polyoxometallolanthanoates - a special class of metal-oxide cluster compounds - which may be considered as models for lanthanide-doped metal-oxide phosphors. This review develops an understanding of molecular mechanisms of energy transfer processes in metal-oxide phosphors, and shows that the oxygen-metal states are involved not only in energy transfer, but also in electron transfer during photoredox reactions, thus making the photochemical design of Mo-blue nano-rings possible.



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